Tetrafluoromethane (CF4, R-14) Gas
Tetrafluoromethane (CF4) is a crucial component in high voltage circuit breakers, particularly when combined with sulfur hexafluoride (SF6) in varying ratios, typically around 10% CF4 to 90% SF6. This gas mixture offers superior electrical insulation and arc-quenching properties, essential for maintaining the integrity and safety of high voltage systems. CF4 enhances the dielectric strength of the mixture, allowing it to withstand significant electrical stresses without breaking down. This property is vital for preventing electrical discharges and ensuring the reliable operation of circuit breakers under high voltage conditions. Additionally, CF4’s thermal stability and chemical inertness contribute to the longevity and reliability of circuit breakers, reducing the need for frequent maintenance and replacement.
In cold weather climates, CF4 provides added benefits by improving the performance of the gas mixture at low temperatures. Ratios can be adjusted to around 20% CF4 to 80% SF6, or even higher, to ensure optimal performance. CF4 helps maintain high dielectric strength and prevents the liquefaction of SF6, ensuring the mixture remains gaseous and effective even in extreme cold. This capability is crucial for the reliable operation of high voltage circuit breakers in harsh environmental conditions. By using CF4 in the gas mixture, the overall environmental impact is also reduced, as it allows for a decrease in the volume of SF6 required. Overall, CF4 is indispensable in enhancing the safety, efficiency, and environmental sustainability of high voltage circuit breakers.
Tetrafluoromethane is also used in semiconductor fabrication to etch the polysilicon, silicon dioxide, and silicon nitride wafers. Concorde can provide a high purity tetrafluoromethane gas for these purposes resulting in a superior and more refined control of the etching process, as well as better dimensional and profile control.
CF4 Safety Requirements
Safety Requirements: The cryogenic CF4 liquid will rapidly boil to gas at standard temperatures and pressures. The liquefied gas can cause frostbite to any contaminated tissue. The main health hazard of releasing this gas is asphyxiation by oxygen displacement (see SDS for further information).
99.2% CF4 Commercial Grade:
CF4 Commercial Grade Maximum Impurities |
|
Tetrafluoromethane |
99.2% |
Nitrogen + Oxygen |
0.7% |
Hexafluoroethane + Carbon Dioxide |
0.1% |
Mass Content of Water |
< 1 ppm |
Acidity |
< 0.1 ppmw |
99.99% CF4 High Purity Grade:
CF4 High Purity Grade Maximum Impurities
|
|
Tetrafluoromethane
|
> 99.99%
|
Oxygen
|
< 5 ppm
|
Nitrogen
|
< 10 ppm
|
Carbon Dioxide + Carbon Monoxide
|
< 2 ppm
|
Other Halocarbons
|
< 2 ppm
|
Sulfur Hexafluoride
|
< 1 ppm
|
Moisture
|
< 2 ppm
|
Acidity (as Hydrogen Fluoride)
|
< 0.1 ppmw
|
Cylinder Specifications |
Contents |
Pressure |
||
Cylinder |
Valve Outlet |
Pounds |
PSIG |
BAR |
40 cf. |
CGA 580 |
12 lb. |
2000 |
139 |
80 cf. |
CGA 580 |
25 lb. |
2000 |
139 |
220 cf. |
CGA580 |
70 lb. |
2000 |
139 |
99.999% CF4 Superior Purity Grade:
CF4 High Purity Grade Maximum Impurities
|
|
Tetrafluoromethane
|
> 99.999%
|
Oxygen + Argon
|
< 1 ppm
|
Nitrogen
|
< 4 ppm
|
Carbon Dioxide + Carbon Monoxide
|
< 1 ppm
|
Other Halocarbons
|
< 2 ppm
|
Sulfur Hexafluoride
|
< 1 ppm
|
Moisture
|
< 1 ppm
|
Acidity (as Hydrogen Fluoride)
|
< 0.1 ppmw
|
Appearance, Safety Requirements:
A compressed, colorless gas, non-flammable, non-explosive, has a moderate general toxic action in inhalation contact.
CF4 Physical Constants |
|
Chemical formula |
CF4 |
Molecular Weight |
80.005 |
Specific volume @ +70°F (+21.1°C) |
4.396 ft³/lb., 0274 m³/kg |
Critical pressure |
542.3. psia, 37.39 bar |
Critical temperature |
-50.17°F, -45.65°C |
Specific gravity @ 70°F, 1 atm (Air=1) |
3.04 |
Hazardous Class |
2.2 |
Label |
Nonflammable Gas |
General Description |
Colorless, Odorless |
Downloads
Variety of Sizes in stock and ready for shipment:
5LB, 11LB, 18LB, 20LB, 25LB, 27.5LB, 35LB, 38LB, 45LB, 50LB, 57LB, 70LB, 90LB, 115LB and 1150LB. Custom Fill available upon request.
5KG, 10KG, 12.5KG, 40KG and 50KG. Custom Fill available upon request.
Concorde Specialty Gases
36 Eaton Road
Eatontown, NJ 07724
Tel: 732-544-9899
We Provide:
SF6 Gas
Recycled SF6 Gas
SF6 Gas Blends
CF4 Gas
Xenon Gas
Krypton Gas
Helium Gas
Dry Air
Custom Gas Blends
International Shipping
ISO 9001:2015 Certified
Concorde Gas Customer Pledge:
- 100% Product Quality Warranty - If any Concorde Gas product fails to meet or exceed our published quality standards, we will provide a full replacement, including all shipping expenses.
- Turnaround in One Business Day or Less - from order to shipment in the Continental US!
- Customer Satisfaction Guarantee - We will do whatever it takes to assure that our customers are completely satisfied with Concorde’s Products and Service.
- Recycling Programs - designed to save you money and do our part for the environment!
Our Services:
- Cylinder Purchase, Rental, Trade-ins
- Customer Cylinder Refills
- Same Day Shipping
- Drop Ship Services
- Private Label (OEM) Programs
- Recycling Services
- Custom Designed Cradle to Grave Programs
- Major Credit Cards Accepted